Qualitative and physical-chemical indicators of chitosan samples and their comparative characteristics with imported analogues
https://doi.org/10.37493/2307-910X.2024.4.6
Abstract
The work is devoted to the study of the qualitative and physicochemical indicators of chitosan obtained by acid-base hydrolysis and enzymatic hydrolysis, and their comparative characteristics with an imported analogue. The introduction identifies the problem in the field of obtaining and using technological auxiliary materials in the beverage industry. The scientific task is to compare the experimentally obtained technological auxiliary materials (chitosan with a deacetylation degree of 62%, insoluble in 1% solutions of organic acids, chitosan with a deacetylation degree of 98%, soluble in 1% solutions of organic acids and imported chitosan (China) in order to obtain import substitution. Classical methods of physicochemical analysis were used as materials and methods to determine the concentration of chemical elements in chitosan samples, a statistical analysis method. It was found that a chitosan sample with a deacetylation degree of 98% has a structure similar to the structure of chitosan produced in China, chitosan with a deacetylation degree of 62% has an amorphous-crystalline structure. In conclusion, a conclusion was made about the compliance of the quality of the obtained samples with the reference chitosan, about the prospects for using chitosan in technological processes taking into account its structural features.
About the Authors
O. V. PavlovaRussian Federation
Oksana V. Pavlova – Cand. Sci. (Techn.), Associate Professor of the Department of Technology, Physiology and Food Hygiene
Grodno
S. S. Anufrik
Russian Federation
Slavamir S. Anufrik – Dr. Sci. (Phys.-Math.), Professor of the Department of Theoretical Physics and Heat Engineering
Grodno
E. I. Eisymont
Russian Federation
Evgenia I. Eisymont – Candidate of Technical Sciences, Associate Professor of the Department of Logistics and Management Methods
Grodno
M. M. Trusova
Russian Federation
Maria M. Trusova – Senior Lecturer of the Department of Technology, Physiology and Nutrition Hygiene
Grodno
References
1. Vliyanie sovmestnoj obrabotki assamblyazhej taninami i belkovymi sorbentami na penistye svojstva vinomaterialov [The influence of joint treatment of assemblages with tannins and protein sorbents on the foamy properties of wine materials] / N. M. Ageeva, A. YU. Danielyan // Vinodelie i vinogradarstvo. 2015. no. 6. pp. 10–13.
2. Primenenie kompleksnyh mineral'nyh sorbentov dlya obrabotki vin [Application of complex mineral sorbents for wine processing] / A. N. Obozhin, N. M. Ageeva, M. G. Markovskij // Izvestiya vysshih uchebnyh zavedenij. Pishchevaya tekhnologiya. 2003. no. 4. pp. 114–115.
3. Guguchkina T. I. Osobennosti importozameshcheniya v vinodelii [Features of import substitution in winemaking] // Nauchnye trudy Severo-Kavkazskogo zonal'nogo nauchno-issledovatel'skogo instituta sadovodstva i vinogradarstva. 2016. Vol. 11. pp. 170–175.
4. Tekhnicheskii reglament Tamozhennogo soyuza 029/2012 «Trebovaniya bezopasnosti pishchevykh dobavok, aromatizatorov i tekhnologicheskikh vspomogatel'nykh sredstv» [Safety requirements for food additives, flavorings and processing aids], 2012. 275 p.
5. Aydın Y. A. Adsorption of chromium on chitosan: Optimization, kinetics and thermodynamics // Chemical Engineering J. 2009. no. 1. pp. 188–194.
6. Intraparticle diffusion processes during acid dye adsorption onto chitosan / W. H. Cheung, Y. S. Szeto, G. McKay // J. Bioresource technology. 2007. no. 15. pp. 2897–2904.
7. Adsorption of food dyes onto chitosan: Optimization process and kinetic / G. L. Dotto, L. A. Pinto // J. Carbohydrate Polymers. 2011. no. 1. pp. 231–238.
8. Equilibrium studies for acid dye adsorption onto chitosan / Y. C. Wong, Y. S. Szeto, W. Cheung, G. McKay // J. Langmuir. 2003. no. 19. pp. 7888–7894.
9. Adsorption mechanism of synthetic reactive dye wastewater by chitosan / N. Sakkayawong, P. Thiravetyan, W. Nakbanpote // Journal of Colloid and Interface Science. 2005. no. 1. pp. 36–42.
10. Role of polymer network and gelation kinetics on the mechanical properties and adsorption capacity of chitosan hydrogels for dye removal / M. Salzano de Luna, R. Altobelli, L. Gioiella, R. Castaldo, G. Scherillo, G. Filippone // J. of Polymer Science Part B: Polymer Physics. 2017. no. 24. pp. 1843–1849.
11. Pavlova O.V., Trusevich B.V. Optimizatsiya uslovii adsorbtsii modifitsirovannogo diatomita [Optimization of adsorption conditions for modified diatomite] // Aktual'nye problemy ekologii: sbornik nauchnykh statei. Grodno: GrGU im. Yanki Kupaly, 2022. pp. 145–147.
12. Il'yasova R. R. Vliyanie stepeni dispersnosti chastits diatomita na ego adsorbtsionnye svoistva po otnosheniyu k ionam medi(II) i serebra(I) [Influence of the degree of dispersion of diatomite particles on its adsorption properties in relation to copper(II) and silver(I) ions] // Khimicheskaya bezopasnost'. 2023. no. 1. pp. 116–127.
13. K. J. Hu Screening of fungi for chitosan producers, and copper adsorption capacity of fungal chitosan and chitosanaceous materials // Carbohydrate Polymers. 2004. no. 1. pp. 45–52.
14. Saywell, L. G. Clarification of wine // Industrial & Engineering Chemistry. 1934. no. 9. pp. 981–982.
15. Pavlova O., Trusova M. Optimisation of conditions for deacetylation of chitin-containing raw materials // Food science and technology. 2021. no. 3. pp. 63–70.
Review
For citations:
Pavlova O.V., Anufrik S.S., Eisymont E.I., Trusova M.M. Qualitative and physical-chemical indicators of chitosan samples and their comparative characteristics with imported analogues. Modern Science and Innovations. 2024;(4):60-72. (In Russ.) https://doi.org/10.37493/2307-910X.2024.4.6